Plasma Spectroscopies, Hyphenation & Speciation

Research group “Plasma Spectroscopies, Hyphenation&Speciation” develops new tools based based on analytical plasmas i.e. ICP-MS, ICP-OES and laser-induced plasma, so called LIBS. The objectives are to quickly identify the nature of a sample from a specific spectral fingerprint, to access traces of target metals and elements in complex samples originating from the environment, new materials or biological samples.

Research areas

Identifying the nature and origin of certain materials is an important issue addressed by our research. Our expertise allows us to develop original tools to study:

  • The geographic origin of different materials such as teas, wines … by combining spectral information obtained using LIBS and ICP-HRMS
  • Characterizing the nature, composition, and size of micro- and nanoparticles using SP-ICP-MS/MS

Research projects

  • The RENOV project (2023-2027, Recycling and Reincorporation of Elastomeric Materials),is funded by the French government, as part of the France 2030 plan (operated by ADEME and financed by the European Union – NextGenerationEU), involves four partners: Elkem, Hutchinson, Nexans, and the Claude Bernard University of Lyon 1 (IMP, CP2M & ISA). It aims to develop a circular economy model for plastics in order to limit their environmental impact, through their collection, recycling, and reintroduction into the manufacturing chain. The SPCS team is in charge of the solid analysis WP, particularly by LIBS spectrometry.
  • CODETEX project funded by the AURA region (2021-2024), this project aims to develop a new protocol for the primary decontamination of firefighters’ fire-resistant textiles, with particle monitoring, their nature, and concentration at the decontamination outlet. LIBS technology and a new SP-ICP-MS method for analyzing these carbon-based particles are being studied.
  • Ultra-trace analysis in complex crystals to confirm the quality and origin of the crystals with the Cristal’Innov platform
  • Collaboration with the IMP Laboratory (IMP, UMR 5233) on monitoring the development and monitoring of “magnetoliposome” nanoparticles. (OPTIMAG-SP-ICP-MS project).

Experimental and instrumental capabilities

Plasma spectroscopy : ICP-MS/MS Agilent 8800, ICP-MS  Agilent 7900, ICP-MS Nexion300 PerkinElmer

ICP-HR-MS ElementXR Thermo and ICP-CCT-QMS X-SerieII Thermo

ICP-OES ICAP Radial + AxialThermo, ICP-OES Axial Vista Agilent

Laser Induced Breakdown Spectroscopy LIBS : Z300 portable Sciaps, Mobilibs II Ivéa
Lasers and spectrometers for LIBS : Minilite Continuum, OceanOptics, HoribaJobinYvon

Sample preparation and separation : microwave Milestone Ethos and Ultrawave ; separation LC Surveyor Thermo et 1290 Agilent, GC 6890 Agilent

Staff

  • Researchers

    • Nadia BASKALI BOUREGAA
    • Nicole GILON

  • Engineers and Technicians

    • Linda AYOUNI-DEROUICHE
    • Frédérique BESSUEILLE

  • Others

    • Chloé BERNARD

Publications (sources HAL)

Journal articles (32 documents )

  • Marie Boutry, Jules Mistral, Paula Oliveira, Nadia Baskali-Bouregaa, Frédérique Bessueille-Barbier, et al.. Development of a Methodology for Analyzing Nanometer‐Sized Iron Oxide by Single Particle ICP-MS Technique. Journal of Analytical Atomic Spectrometry, 2024, 39 (7), pp.1726-1735. ?10.1039/D4JA00022F?. ?hal-04581249?
  • Jad Sahili, Tessa Reinert, Nadia Baskali-Bouregaa, Anthony Desert, Nicole Gilon. Nano objects evaluation for nanoparticle enhanced laser induced breakdown spectroscopy analysis of polymers using a handheld device. Spectrochimica Acta Part B: Atomic Spectroscopy, 2023, 205, pp.106697. ?10.1016/j.sab.2023.106697?. ?hal-04155275?
  • Nicole Gilon, Margaux Soyer, Mathilde Redon, Patrice Fauvet. Separation of Leather, Synthetic Leather and Polymers Using Handheld Laser-Induced Breakdown Spectroscopy. Sensors, 2023, 23 (5), pp.2648. ?10.3390/s23052648?. ?hal-04008795?
  • Mor Mbodji, Nadia Baskali-Bouregaa, Frédérique Barbier-Bessueille, Linda Ayouni-Derouiche, Cheikh Diop, et al.. Speciation of metals by sequential extractions of agricultural soils located near a dumpsite for prediction of element availability to vegetables. Talanta, 2022, 244, pp.123411. ?10.1016/j.talanta.2022.123411?. ?hal-03675539?
  • Mor Mbodji, Nadia Baskali-Bouregaa, Frédérique Bessueille, Robert Faomowe-Foko, Mamadou Fall, et al.. Investigating the metal contamination status from recycling e-waste sites from Dakar, Senegal. Environmental Science and Pollution Research, 2022, ?10.1007/s11356-021-17678-x?. ?hal-03523115?
  • Linda Ayouni-Derouiche, Frédérique Barbier-Bessueille, Nicole Gilon, Agnès Hagège. Analyse de traces et d’ultra-traces d’éléments. Les Techniques de l'Ingenieur, 2021, pp.P3860 V4. ?10.51257/a-v4-p3860?. ?hal-03508164?
  • Niall O'Toole, Constance Lecourt, Yan Suffren, Francois Toche, Rodica Chiriac, et al.. Intercalation of a manganese(II)-thiacalixarene luminescent complex in layered double hydroxides: synthesis and photophysical characterization. New Journal of Chemistry, 2021, 45 (1), pp.343-350. ?10.1039/d0nj04890a?. ?hal-03127398?
  • Nadia Baskali-Bouregaa, Marie-Laure Milliand, Sophie Mauffrey, Elodie Chabert, Maureen Forrestier, et al.. Tea geographical origin explained by LIBS elemental profile combined to isotopic information. Talanta, 2020, 211, pp.120674. ?10.1016/j.talanta.2019.120674?. ?hal-02456974?
  • Marie Bernardin, Agnès Le Masle, Frédérique Bessueille-Barbier, Charles-Philippe Lienemann, Sabine Heinisch. Comprehensive two-dimensional liquid chromatography with inductively coupled plasma mass spectrometry detection for the characterization of sulfur, vanadium and nickel compounds in petroleum products. Journal of Chromatography A, 2020, 1611, pp.460605. ?10.1016/j.chroma.2019.460605?. ?hal-02442806?
  • Marie Bernardin, Frédérique Bessueille-Barbier, Agnès Le Masle, Charles-Philippe Lienemann, Sabine Heinisch. Suitable interface for coupling liquid chromatography to inductively coupled plasma-mass spectrometry for the analysis of organic matrices. 2 Comparison of Sample Introduction Systems. Journal of Chromatography A, 2019, 1603, pp.380-387. ?10.1016/j.chroma.2019.04.074?. ?hal-02162840?
  • Chen Sun, Ye Tian, Liang Gao, Yishuai Niu, Tianlong Zhang, et al.. Machine Learning Allows Calibration Models to Predict Trace Element Concentration in Soils with Generalized LIBS Spectra. Scientific Reports, 2019, 9 (1), ?10.1038/s41598-019-47751-y?. ?hal-02276189?
  • Fabien Chainet, Alain Desprez, Sylvain Carbonneaux, Linda Ayouni, Marie-Laure Milliand, et al.. Investigation of the potential of the ICP-MS/MS for total and speciation analysis in petroleum fractions. Fuel Processing Technology, 2019, 188, pp.60-69. ?10.1016/j.fuproc.2019.01.013?. ?hal-02091325?
  • Mohamed Anouar Nouioui, Manel Araoud, Marie-Laure Milliand, Frédérique Bessueille-Barbier, Dorra Amira, et al.. Biomonitoring chronic lead exposure among battery manufacturing workers in Tunisia. Environmental Science and Pollution Research, 2019, 26 (8), pp.7980-7993. ?10.1007/s11356-019-04209-y?. ?hal-02162866?
  • Marie Bretier, Aymeric Dabrin, Frédérique Barbier-Bessueille, Marina Coquery. The impact of dam flushing event on dissolved trace elements concentrations: Coupling integrative passive sampling and discrete monitoring. Science of the Total Environment, 2019, 656, pp.433-446. ?10.1016/j.scitotenv.2018.11.303?. ?hal-01937679?
  • Mohamed Anouar Nouioui, Manel Araoud, Marie-Laure Milliand, Frédérique Bessueille-Barbier, Dorra Amira, et al.. Evaluation of the status and the relationship between essential and toxic elements in the hair of occupationally exposed workers. Environmental Monitoring and Assessment, 2018, 190 (12). ?hal-01947745?
  • Mohamed Anouar Nouioui, Marie-Laure Milliand, Frédérique Bessueille-Barbier, Abderrazek Hedhili, Linda Ayouni-Derouiche. Determination of traces of As, Cd, Cr, Hg, Mn, Ni, Sb, Se, Sn and Pb in human hair by triple quadrupole ICP-MS. International Journal of Environmental Analytical Chemistry, 2018, 98 (10), pp.954-976. ?10.1080/03067319.2018.1517870?. ?hal-01900221?
  • Marie Bernardin, Frédérique Bessueille-Barbier, Agnès Le Masle, Charles-Philippe Lienemann, Sabine Heinisch. Suitable interface for coupling liquid chromatography to inductively coupled plasma-mass spectrometry for the analysis of organic matrices. 1 Theoretical and experimental considerations on solute dispersion. Journal of Chromatography A, 2018, 1565, pp.68-80. ?10.1016/j.chroma.2018.06.024?. ?hal-01858414?
  • Laure Wiest, Teofana Chonova, Alexandre Bergé, Robert Baudot, Frédérique Bessueille-Barbier, et al.. Two-year survey of specific hospital wastewater treatment and its impact on pharmaceutical discharges. Environmental Science and Pollution Research, 2018, 25 (10), pp.9207-9218. ?10.1007/s11356-017-9662-5?. ?hal-01569749?
  • Jana Bocková, Ye Tian, Hualiang Yin, Nicole Delepine-Gilon, Yanping Chen, et al.. Determination of Metal Elements in Wine Using Laser-Induced Breakdown Spectroscopy (LIBS). Applied Spectroscopy, 2017, 71 (8), ?10.1177/0003702817708337?. ?hal-01569738?
  • Ye Tian, Chunhua Yan, Tianlong Zhang, Hongsheng Tang, Hua Li, et al.. Classification of wines according to their production regions with the contained trace elements using laser-induced breakdown spectroscopy. Spectrochimica Acta Part B: Atomic Spectroscopy, 2017, 135, pp.91-101. ?10.1016/j.sab.2017.07.003?. ?hal-01569772?
  • Ye Tian, Hoi Ching Cheung, Ronger Zheng, Qianli Ma, Yanping Chen, et al.. Elemental analysis of powders with surface-assisted thin film laser-induced breakdown spectroscopy. Spectrochimica Acta Part B: Atomic Spectroscopy, 2016, 124, pp.16-24. ?10.1016/j.sab.2016.08.016?. ?hal-01569760?
  • Laure Ridel, Marie-Alexandrine Bolzinger, Nicole Delépine-Gilon, Pierre-Yves Dugas, Yves Chevalier. Pickering emulsions stabilized by charged nanoparticles.. Soft Matter, 2016, 12 (36), pp.7564-7576. ?10.1039/c6sm01465h?. ?hal-01546567?
  • Raphael Paweloszek, Stéphanie Briançon, Yves Chevalier, Nicole Delépine-Gilon, Jocelyne Pelletier, et al.. Skin absorption of anions: part one. Methodology for in vitro cutaneousabsorption measurements. Pharmaceutical Research, 2016, 33 (7), pp.1564-1575. ?10.1007/s11095-016-1909-1?. ?hal-01357982?
  • Raphael Paweloszek, Stéphanie Briançon, Yves Chevalier, Nicole Gilon, Jocelyne Pelletier, et al.. Skin absorption of anions: part two. Skin absorption of halide ions. Pharmaceutical Research, 2016, 33 (7), pp.1576-1586. ?10.1007/s11095-016-1898-0?. ?hal-01357986?
  • Florian Trichard, Valérian Forquet, Nicole Delépine-Gilon, C. P. Lienemann, Franck Baco-Antoniali. Detection and quantification of sulfur in oil products by laser-induced breakdown spectroscopy for on-line analysis. Spectrochimica Acta Part B: Atomic Spectroscopy, 2016, 118, pp.72-80. ?10.1016/j.sab.2016.02.001?. ?hal-01357854?
  • Florian Trichard, Nicole Delépine-Gilon, Charles-Philippe Lienemann, Franck Baco-Antoniali. Evaluation of laser induced breakdown spectroscopy in view of nickel and vanadium online determination in petroleum products. Journal of Analytical Atomic Spectrometry, 2016, 31 (3), pp.712-721. ?10.1039/c5ja00421g?. ?hal-01338341?
  • Jérôme Menneveux, Fang Wang, Shan Lu, Xueshi Bai Bai, Vincent Motto-Ros, et al.. Direct determination of Ti content in sunscreens with laser-induced breakdown spectroscopy: Line selection method for high TiO2 nanoparticle concentration. Spectrochimica Acta Part B: Atomic Spectroscopy, 2015, 109, pp.9-15. ?10.1016/j.sab.2015.04.010?. ?hal-01186952?
  • Linda Ayouni-Derouiche, Marie Méjean, Marie-Laure Milliand, Pierre Lantéri, Laury Gauthier, et al.. Development of efficient digestion procedures for quantitative determination of cobalt and molybdenum catalyst residues in carbon nanotubes. Carbon, 2014, 80, pp.59-67. ?10.1016/j.carbon.2014.08.025?. ?hal-01077228?
  • Danilo C Vasconcelos, Claubia Pereira, Arno Heeren de Oliveira, Mário R. S Silva, Fernando R Carvalho, et al.. Study of metal and trace metals in shrimps Macrobrachium rosenbergii in creating captivity, aimed at domestic consumption and export.. Global Advanced Research Journal of Agricultural Science, 2014, 3 (11), pp.367-372. ?hal-01357896?
  • T. C. Oliveira, R. P. G. Monteiro, G. F. Kastner, Frédérique Bessueille-Barbier, A. H. Oliveira. Radiochemical methodologies applied to determination of zirconium isotopes in low-level waste samples from nuclear power plants. Journal of Radioanalytical and Nuclear Chemistry, 2014, 302 (1), pp.41-47. ?10.1007/s10967-014-3283-y?. ?hal-01364818?
  • Lijuan Zheng, Fan Cao, Junshan Xiu, Xueshi Bai, Vincent Motto-Ros, et al.. On the performance of laser-induced breakdown spectroscopy for direct determination of trace metals in lubricating oils. Spectrochimica Acta Part B: Atomic Spectroscopy, 2014, 99, pp.1-8. ?10.1016/j.sab.2014.06.005?. ?hal-01070740?
  • C. B. Faye, T. Amodeo, E. Fréjafon, Nicole Delépine-Gilon, C. Dutouquet. Sampling considerations when analyzing micrometric-sized particles in a liquid jet using laser induced breakdown spectroscopy. Spectrochimica Acta Part B: Atomic Spectroscopy, 2014, 91, pp.5-11. ?10.1016/j.sab.2013.10.009?. ?hal-00954547?